Nomenclature of Elements with Atomic Numbers > 100
Superheavy elements triggered a Cold War of names — two countries, two names, one element. IUPAC’s truce: ten digit roots that give every element from 100 to 999 a neutral, temporary name, no diplomacy required. Ten roots, two spelling rules, one live decoder.
Why New Names Were Needed — Complete Theory
Synthesis raced ahead of diplomacy. When labs in different countries claimed the same new superheavy element, each proposed its own name: element 104 was rutherfordium to the Americans and kurchatovium to the Soviets; element 105 was hahnium to one camp and nielsbohrium to another. Textbooks split, students suffered, and the table grew embarrassing footnotes. IUPAC’s fix: a neutral, systematic temporary name derived mechanically from the atomic number — used until the discovery claim is settled and a permanent name is agreed (most were, by 1997).
The machinery is delightfully small. Ten digit-roots stand for the digits 0–9; the digits of the atomic number are replaced by their roots in order; the ending -ium is appended for the name; and the first letters of the roots form a three-letter temporary symbol (first letter capitalised).
| Digit | Root | Letter | Digit | Root | Letter |
|---|---|---|---|---|---|
| 0 | nil | n | 5 | pent | p |
| 1 | un | u | 6 | hex | h |
| 2 | bi | b | 7 | sept | s |
| 3 | tri | t | 8 | oct | o |
| 4 | quad | q | 9 | enn | e |
| Z | Temporary name | Symbol | Permanent name | Permanent symbol |
|---|---|---|---|---|
| 101 | unnilunium | Unu | Mendelevium (Md) | |
| 102 | unnilbium | Unb | Nobelium (No) | |
| 103 | unniltrium | Unt | Lawrencium (Lr) | |
| 109 | unnilennium | Une | Meitnerium (Mt) | |
| 110 | ununnilium | Uun | Darmstadtium (Ds) | |
| 111 | unununium | Uuu | Roentgenium (Rg) |
Two spelling adjustments keep the names pronounceable, and both are exam favourites: when enn (9) is followed by nil (0), one “n” is dropped — enn + nil → ennil, so 190 is unennilium, not “unennnilium”; and when bi (2) or tri (3) is followed by the ending -ium, one “i” is dropped — bi + ium → bium, tri + ium → trium, so 112 is ununbium and 113 is ununtrium. Crucially, the symbol ignores these adjustments — it always reads the raw digit-roots: 190 is Uen (u-e-n) even though its name spells “ennil”.
Visualising the Pipeline & Decoding Any Z
Ek pipeline, ek decoder — watch 109 build itself first, then feed the decoder any Z from 101 to 199.
Nomenclature Decoder
Spelling adjustments fire live: watch “nnn → nn” on 190 and “ii → i” on 102/103/112/113 — while the symbol keeps the raw digit-roots. For Z ≥ 119 the temporary name is the only name that exists.
Solved Examples (Step-by-Step)
Digits → roots → name → symbol. Jo chain yahan chalti hai, wahi decoder me live chalti hai.
Z = 114, no adjustments needed
Write the temporary IUPAC name and symbol for the element with Z = 114, and give its permanent name.
- Digits
1, 1, 4→ rootsun, un, quad - Name+ ium →
ununquadium— quad ends in “d”, no “ii” clash, rule-free ✓ - Symbol
u + u + q → Uuq - PermanentSettled as Flerovium (Fl) — verify on the decoder.
ununquadium (Uuq) → Flerovium (Fl)
Z = 190: where “nnn” must shrink
Write the temporary name and symbol for Z = 190, showing the spelling adjustment explicitly.
- Digits
1, 9, 0→ rootsun, enn, nil - Raw join+ ium →
unennnilium— contains the illegal triple-n. - Adjustenn + nil → ennil (drop one “n”) →
unennilium - SymbolDigit-letters
u, e, n → Uen— not “Unn”: the symbol reads digits, ignoring the adjusted spelling.
unennilium · symbol Uen — rule fired, symbol unbothered
From “unbihexium” back to Z
An old problem sheet refers to “unbihexium (Ubh)”. Recover its atomic number and say whether it has a permanent name.
- Split roots
un · bi · hex→ digits1, 2, 6 - Z
Z = 126— symbol check: u-b-h → Ubh ✓ - StatusZ = 126 lies beyond 118 — never synthesised, so the temporary name is its only name. Reverse decoding is how examiners test the root table itself.
Z = 126 · Ubh — unnamed, and correctly so
Practice Questions (With Solutions)
Attempt first — options lock after one shot, exactly like the real exam. Then read the working, chahe galti ho ya na ho.
Attempted 0/4 · Correct 0
The IUPAC temporary name and symbol for the element with Z = 111 are:
Solution
- 111 → 1,1,1 → un·un·un + ium = unununium, symbol Uuu — now roentgenium (Rg).
- Option A is 110’s name; C is 109’s; D is 112’s — the decoder catches all three instantly.
(B) unununium, Uuu
When the root “enn” is followed by the root “nil”, the combined name:
Solution
- Exactly one “n” is dropped: enn + nil = ennil — so 190 is unennilium.
- The letter-count must stay sensible; and the symbol still reads the raw digits (Uen), whatever the spelling does.
(B) Drop one n → ennil
The temporary name of the element with Z = 120 is:
- 120 → 1,2,0 → un·bi·nil + ium. “bi” is followed by “nil”, not by “ium” — no i-drop fires → unbinilium.
- Symbols are always three letters (B is wrong twice); the leading “un” for digit 1 is never optional (D).
(A) unbinilium (Ubn)
The temporary symbol “Ubh” corresponds to the atomic number:
- U-b-h → u = 1, b = 2, h = 6 → Z = 126 (unbihexium).
- Option A reverses the digit order; C reads letters as numbers; D misreads h as 9.
(B) 126
Key Rules & Takeaways
Eight lines that solve this topic
Disputes: 104 rutherfordium vs kurchatovium · 105 hahnium vs nielsbohrium · NCERT examples: 101 Unu · 102 Unb · 103 Unt · 109 Une · 110 Uun · 111 Uuu
- Ten roots name nine hundred elements — the whole system is a digit-to-syllable cipher with an -ium tail.
- Two adjustments, two vowels — enn+nil drops an “n”; bi/tri+ium drops an “i”. Quote them exactly; they are one-mark questions.
- Symbol and spelling live apart — the symbol reads raw digit-roots (190 → Uen), the name takes the pronounceable form (unennilium).
- Temp names are scaffolding — 101–118 now carry permanent names; for never-made elements (Z ≥ 119), the temporary name is the only name.
FAQs
Why were systematic temporary names needed for elements with Z > 100?
Discoveries of superheavy elements often involved competing claims from laboratories in different countries, and each lab proposed its own name — element 104 was called rutherfordium by Americans and kurchatovium by Soviet scientists. To end such disputes, IUPAC adopted a neutral, systematic naming scheme: a temporary name built from digit roots, used until the discovery claim is settled and a permanent name is agreed.
What are the IUPAC digit roots from 0 to 9?
0 = nil (n), 1 = un (u), 2 = bi (b), 3 = tri (t), 4 = quad (q), 5 = pent (p), 6 = hex (h), 7 = sept (s), 8 = oct (o) and 9 = enn (e). The digits of the atomic number are replaced by these roots in order, the ending -ium is added for the name, and the first letters of the roots give the three-letter temporary symbol.
What is the temporary name and symbol of element 110?
Element 110 = digits 1, 1, 0 = un + un + nil + ium = ununnilium, with the temporary symbol Uun. It has since received the permanent name darmstadtium (Ds). Similarly, 111 = unununium (Uuu), now roentgenium (Rg).
What spelling adjustments apply when combining the digit roots?
Two adjustments apply: when enn (9) is followed by nil (0), one n is dropped — enn + nil = ennil, so 190 is unennilium, not unennnilium; and when bi (2) or tri (3) is followed by the ending -ium, one i is dropped — bi + ium = bium and tri + ium = trium, so 112 is ununbium and 113 is ununtrium. The three-letter symbol, however, always uses the raw digit roots.
Saved on this device only — no account, no sign-in.